Investigating carbocations using high speed ball milling
| Main Author: | |
|---|---|
| Language: | English |
| Published: |
University of Cincinnati / OhioLINK
2012
|
| Subjects: | |
| Online Access: | http://rave.ohiolink.edu/etdc/view?acc_num=ucin1352402944 |
| id |
ndltd-OhioLink-oai-etd.ohiolink.edu-ucin1352402944 |
|---|---|
| record_format |
oai_dc |
| spelling |
ndltd-OhioLink-oai-etd.ohiolink.edu-ucin13524029442021-08-03T05:20:30Z Investigating carbocations using high speed ball milling Wagner, Meghan Chemistry Carbocations are typically formed in solution, where the solvent stabilizes thecarbocation and mixes the reaction allowing the particles to interact and form products. However, in the absence of solvent it is unknown if the carbocation will form. Previous literature has shown that S<sub>N</sub>2 reactions can occur under high speed ball milling conditions; the results were that primary alkyl halides undergo substitution reactions, while the reactions of secondary alkyl halides depend on the nucleophile. However, reactions that form a carbocation intermediate, such as, S<sub>N</sub>1 reaction and pinacol rearrangement have not been explored, until now. 2012 English text University of Cincinnati / OhioLINK http://rave.ohiolink.edu/etdc/view?acc_num=ucin1352402944 http://rave.ohiolink.edu/etdc/view?acc_num=ucin1352402944 unrestricted This thesis or dissertation is protected by copyright: all rights reserved. It may not be copied or redistributed beyond the terms of applicable copyright laws. |
| collection |
NDLTD |
| language |
English |
| sources |
NDLTD |
| topic |
Chemistry |
| spellingShingle |
Chemistry Wagner, Meghan Investigating carbocations using high speed ball milling |
| author |
Wagner, Meghan |
| author_facet |
Wagner, Meghan |
| author_sort |
Wagner, Meghan |
| title |
Investigating carbocations using high speed ball milling |
| title_short |
Investigating carbocations using high speed ball milling |
| title_full |
Investigating carbocations using high speed ball milling |
| title_fullStr |
Investigating carbocations using high speed ball milling |
| title_full_unstemmed |
Investigating carbocations using high speed ball milling |
| title_sort |
investigating carbocations using high speed ball milling |
| publisher |
University of Cincinnati / OhioLINK |
| publishDate |
2012 |
| url |
http://rave.ohiolink.edu/etdc/view?acc_num=ucin1352402944 |
| work_keys_str_mv |
AT wagnermeghan investigatingcarbocationsusinghighspeedballmilling |
| _version_ |
1719418878633705472 |