The Design and Synthesis of Corannulene-Based Nanomaterial

The Design and Synthesis of Corannulene-Based Nanomaterial

Bibliographic Details
Main Author: Hurst, Angela L.
Language:English
Published: University of Cincinnati / OhioLINK 2010
Subjects:
Organic Chemistry
Corannulene
optical limiting capabilities
fullerenes
electrochromic properties
enedyine moiety
conjugated molcules
Online Access:http://rave.ohiolink.edu/etdc/view?acc_num=ucin1271706999
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spelling ndltd-OhioLink-oai-etd.ohiolink.edu-ucin12717069992021-08-03T06:13:52Z The Design and Synthesis of Corannulene-Based Nanomaterial Hurst, Angela L. Organic Chemistry Corannulene optical limiting capabilities fullerenes electrochromic properties enedyine moiety conjugated molcules Theoretical density functional theory (B3LYP) calculations were performed on <i>cis(bis)corannulene enediyne, trans (bis) corannulene enediyne, vinylic ethyl corannulene enediyne, and tetra ethlycorannulene enediyne.</i> The results indicate a max wavelength of 454, 466, 380, respectively; <i>tetra ethlycorannulene enediyne</i> unknown. Highly conjugated molecules with an enedyine moiety are expected to exhibit electrical conductivity, and electrochromic properties, as well as optical limiting capabilities. We envision using fullerene fragments (corannulene) as templates to study its electrical conducting abilities. The focus of this research has been the synthesis and conditions necessary for the fabrication of various corannulene substituted ethylene structures which show a wavelength of 1100nm or greater. 2010-04-19 English text University of Cincinnati / OhioLINK http://rave.ohiolink.edu/etdc/view?acc_num=ucin1271706999 http://rave.ohiolink.edu/etdc/view?acc_num=ucin1271706999 unrestricted This thesis or dissertation is protected by copyright: all rights reserved. It may not be copied or redistributed beyond the terms of applicable copyright laws.
collection NDLTD
language English
sources NDLTD
topic Organic Chemistry
Corannulene
optical limiting capabilities
fullerenes
electrochromic properties
enedyine moiety
conjugated molcules
spellingShingle Organic Chemistry
Corannulene
optical limiting capabilities
fullerenes
electrochromic properties
enedyine moiety
conjugated molcules
Hurst, Angela L.
The Design and Synthesis of Corannulene-Based Nanomaterial
author Hurst, Angela L.
author_facet Hurst, Angela L.
author_sort Hurst, Angela L.
title The Design and Synthesis of Corannulene-Based Nanomaterial
title_short The Design and Synthesis of Corannulene-Based Nanomaterial
title_full The Design and Synthesis of Corannulene-Based Nanomaterial
title_fullStr The Design and Synthesis of Corannulene-Based Nanomaterial
title_full_unstemmed The Design and Synthesis of Corannulene-Based Nanomaterial
title_sort design and synthesis of corannulene-based nanomaterial
publisher University of Cincinnati / OhioLINK
publishDate 2010
url http://rave.ohiolink.edu/etdc/view?acc_num=ucin1271706999
work_keys_str_mv AT hurstangelal thedesignandsynthesisofcorannulenebasednanomaterial
AT hurstangelal designandsynthesisofcorannulenebasednanomaterial
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