Development of Conductive Green Polymer Nano-Composite for use in Construction of Transportation Infrastructure

Bibliographic Details
Main Author: Gissentaner, Tremaine D.
Language:English
Published: Ohio University / OhioLINK 2014
Subjects:
PLA
Online Access:http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1408697877
id ndltd-OhioLink-oai-etd.ohiolink.edu-ohiou1408697877
record_format oai_dc
spelling ndltd-OhioLink-oai-etd.ohiolink.edu-ohiou14086978772021-08-03T06:27:12Z Development of Conductive Green Polymer Nano-Composite for use in Construction of Transportation Infrastructure Gissentaner, Tremaine D. Civil Engineering Nanocomposites Nano-composites Carbon Nanofibers Polylactic Acid PLA Green Polymers This thesis evaluates the effects of graphite based carbon nanofibers (CNF) when incorporated within a NatureWorks Ingeo 3001D Polylactide (PLA) matrix. A film casting method was conducted in which CNF was mixed via sonication with neat PLA at 1% wt., 3% wt., and 5% wt. doses in aims of enhancing nanomechanical behavior and conductivity. A melt compounding method via twin extrusion, was also performed to fabricate PLA/CNF samples at the same CNF wt. doses as employed by the film casting method. Nanocharacterization of samples were performed via Atomic Force Microscopy (AFM) and Scanning Electron Microscopy to evaluate nanomechanical properties and nano/micro structure of PLA/CNF samples. The PLA/1%wt. CNF sample mechanically performed better than the neat PLA, 3%, and 5% CNF samples for the film cast (69,996.94 ± 4,545.29 psi) and extruded (95,111.72 ± 30,388.96 psi) methods with respect to AFM nanoindentation. Macroscale tensile testing was performed effectively extruded samples in which the PLA/3%wt. CNF loading case (Young's Modulus = 295,594.18 psi) performed the best. Conductivity measurements were also completed to evaluate the potential for PLA/CNF based nanocomposites to be considered electrical sensors for civil engineering applications. The PLA/5%wt. CNF film cast sample was found to possess the most favorable electrical resistance (859.45 O), while all other samples were deemed not conductive due to improper dispersion of CNF particulates. 2014 English text Ohio University / OhioLINK http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1408697877 http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1408697877 unrestricted This thesis or dissertation is protected by copyright: all rights reserved. It may not be copied or redistributed beyond the terms of applicable copyright laws.
collection NDLTD
language English
sources NDLTD
topic Civil Engineering
Nanocomposites
Nano-composites
Carbon Nanofibers
Polylactic Acid
PLA
Green Polymers
spellingShingle Civil Engineering
Nanocomposites
Nano-composites
Carbon Nanofibers
Polylactic Acid
PLA
Green Polymers
Gissentaner, Tremaine D.
Development of Conductive Green Polymer Nano-Composite for use in Construction of Transportation Infrastructure
author Gissentaner, Tremaine D.
author_facet Gissentaner, Tremaine D.
author_sort Gissentaner, Tremaine D.
title Development of Conductive Green Polymer Nano-Composite for use in Construction of Transportation Infrastructure
title_short Development of Conductive Green Polymer Nano-Composite for use in Construction of Transportation Infrastructure
title_full Development of Conductive Green Polymer Nano-Composite for use in Construction of Transportation Infrastructure
title_fullStr Development of Conductive Green Polymer Nano-Composite for use in Construction of Transportation Infrastructure
title_full_unstemmed Development of Conductive Green Polymer Nano-Composite for use in Construction of Transportation Infrastructure
title_sort development of conductive green polymer nano-composite for use in construction of transportation infrastructure
publisher Ohio University / OhioLINK
publishDate 2014
url http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1408697877
work_keys_str_mv AT gissentanertremained developmentofconductivegreenpolymernanocompositeforuseinconstructionoftransportationinfrastructure
_version_ 1719436782828781568