FORMATION OF C-C COVALENT BOND ON THE SURFACE OF POLY (CHLOROTRIFLUOROETHYLENE) BY SUBSTITUTION

FORMATION OF C-C COVALENT BOND ON THE SURFACE OF POLY (CHLOROTRIFLUOROETHYLENE) BY SUBSTITUTION

Bibliographic Details
Main Author: Mazi, Wafa A.
Language:English
Published: Miami University / OhioLINK 2010
Subjects:
Chemistry
PCTFE
NaS2O4
DMSO
Zn/Pd
NiCl2
Mg
Cu/ PPh3
acetonitrile
DMF
Online Access:http://rave.ohiolink.edu/etdc/view?acc_num=miami1292027447
id ndltd-OhioLink-oai-etd.ohiolink.edu-miami1292027447
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spelling ndltd-OhioLink-oai-etd.ohiolink.edu-miami12920274472021-08-03T05:41:09Z FORMATION OF C-C COVALENT BOND ON THE SURFACE OF POLY (CHLOROTRIFLUOROETHYLENE) BY SUBSTITUTION Mazi, Wafa A. Chemistry PCTFE NaS2O4 DMSO Zn/Pd NiCl2 Mg Cu/ PPh3 acetonitrile DMF Previous work by our group showed the poly (chlorotrifluoroethylene) can be functionalized by one electron reduction followed by radical trapping. Several new methods for such reduction were examined including Cu / phenanthroline in dimethyl sulfoxide (DMSO), NaS2O4, in DMSO, Zn/Pd in tetrahydrofuran (THF), chloro (pyridine) cobaloxime (III) with Mg in THF, and NiCl2, Mg0 or Cu/ PPh3 in dimethylformamide (DMF) or acetonitrile.The most promising systems were found to be NiCl2, Mg0/ PPh3, but the choice of trapping agent and solvent was crucial. Trapping with acrylonitrile, dihydropyran, butyl acrylate, and styrene were successful. Further reactions of styrylated PCTFE were carried out. 2010-12-13 English text Miami University / OhioLINK http://rave.ohiolink.edu/etdc/view?acc_num=miami1292027447 http://rave.ohiolink.edu/etdc/view?acc_num=miami1292027447 unrestricted This thesis or dissertation is protected by copyright: all rights reserved. It may not be copied or redistributed beyond the terms of applicable copyright laws.
collection NDLTD
language English
sources NDLTD
topic Chemistry
PCTFE
NaS2O4
DMSO
Zn/Pd
NiCl2
Mg
Cu/ PPh3
acetonitrile
DMF
spellingShingle Chemistry
PCTFE
NaS2O4
DMSO
Zn/Pd
NiCl2
Mg
Cu/ PPh3
acetonitrile
DMF
Mazi, Wafa A.
FORMATION OF C-C COVALENT BOND ON THE SURFACE OF POLY (CHLOROTRIFLUOROETHYLENE) BY SUBSTITUTION
author Mazi, Wafa A.
author_facet Mazi, Wafa A.
author_sort Mazi, Wafa A.
title FORMATION OF C-C COVALENT BOND ON THE SURFACE OF POLY (CHLOROTRIFLUOROETHYLENE) BY SUBSTITUTION
title_short FORMATION OF C-C COVALENT BOND ON THE SURFACE OF POLY (CHLOROTRIFLUOROETHYLENE) BY SUBSTITUTION
title_full FORMATION OF C-C COVALENT BOND ON THE SURFACE OF POLY (CHLOROTRIFLUOROETHYLENE) BY SUBSTITUTION
title_fullStr FORMATION OF C-C COVALENT BOND ON THE SURFACE OF POLY (CHLOROTRIFLUOROETHYLENE) BY SUBSTITUTION
title_full_unstemmed FORMATION OF C-C COVALENT BOND ON THE SURFACE OF POLY (CHLOROTRIFLUOROETHYLENE) BY SUBSTITUTION
title_sort formation of c-c covalent bond on the surface of poly (chlorotrifluoroethylene) by substitution
publisher Miami University / OhioLINK
publishDate 2010
url http://rave.ohiolink.edu/etdc/view?acc_num=miami1292027447
work_keys_str_mv AT maziwafaa formationofcccovalentbondonthesurfaceofpolychlorotrifluoroethylenebysubstitution
_version_ 1719423591901036544

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