Synthesis of Novel Hydrogen-Bonding Unit for Organic Field-Effect Transistors

Synthesis of Novel Hydrogen-Bonding Unit for Organic Field-Effect Transistors

Bibliographic Details
Main Author: Jin, Jiyang
Language:English
Published: University of Akron / OhioLINK 2016
Subjects:
Chemistry
Polymer Chemistry
Organic field effect transistor
Latent hydrogen-bond unit
Pigment PB 80
DTPO
DTP
Online Access:http://rave.ohiolink.edu/etdc/view?acc_num=akron1460047707
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spelling ndltd-OhioLink-oai-etd.ohiolink.edu-akron14600477072021-08-03T06:35:19Z Synthesis of Novel Hydrogen-Bonding Unit for Organic Field-Effect Transistors Jin, Jiyang Chemistry Polymer Chemistry Organic field effect transistor Latent hydrogen-bond unit Pigment PB 80 DTPO DTP Organic semiconductors have attracted increasing attention because of their potential in making low cost, flexible and large area electronic devices. For organic field-effect transistors (OFETs), the charge transport in the semiconductor materials is not only affected by their intrinsic electronic properties, but also by their intermolecular packing mode in the solid states. Intermolecular hydrogen-bond is one of the strategy to provide extra intermolecular interaction and enhance packing of polymer chains. Inspired by our previous work1, an novel conjugated structure dithieno[3,2-b:2,3-d]Pyridin-5(4H)-one (DTP) has been synthesized and characterized. The DTP structure possesses two fused thiophene units,which can be good electron donor ,and a d-lactam unit in which can be functionalized with alkyl or t-Boc groups to provide sufficient solubility for solution processing. Originally published as a blue pigment2, Diimidazo[4,5-¿b:4',5'-m]triphenodioxazine-2,10-dione,6,14-dichloro-1,3,9,11-tetrahydro, also named Pigment Blue 80 (P.B 80) is believed to have good potential as organic electronics. The pigment molecule has big conjugated triphenodioxazine structure with two imdazo-2-one rings as hydrogen-bonding sites, as well as two chlorine atoms to provide potential in polymerization. Different routes has been tried in order to synthesis the P.B 80 molecule, an important intermediate 5-amino-6-methoxy-1,3-dihydro-2H-benzo[d]imidazol-2-one has been synthesized and characterized, and the reaction condition in critical steps has been studied. 2016-06-10 English text University of Akron / OhioLINK http://rave.ohiolink.edu/etdc/view?acc_num=akron1460047707 http://rave.ohiolink.edu/etdc/view?acc_num=akron1460047707 unrestricted This thesis or dissertation is protected by copyright: some rights reserved. It is licensed for use under a Creative Commons license. Specific terms and permissions are available from this document's record in the OhioLINK ETD Center.
collection NDLTD
language English
sources NDLTD
topic Chemistry
Polymer Chemistry
Organic field effect transistor
Latent hydrogen-bond unit
Pigment PB 80
DTPO
DTP
spellingShingle Chemistry
Polymer Chemistry
Organic field effect transistor
Latent hydrogen-bond unit
Pigment PB 80
DTPO
DTP
Jin, Jiyang
Synthesis of Novel Hydrogen-Bonding Unit for Organic Field-Effect Transistors
author Jin, Jiyang
author_facet Jin, Jiyang
author_sort Jin, Jiyang
title Synthesis of Novel Hydrogen-Bonding Unit for Organic Field-Effect Transistors
title_short Synthesis of Novel Hydrogen-Bonding Unit for Organic Field-Effect Transistors
title_full Synthesis of Novel Hydrogen-Bonding Unit for Organic Field-Effect Transistors
title_fullStr Synthesis of Novel Hydrogen-Bonding Unit for Organic Field-Effect Transistors
title_full_unstemmed Synthesis of Novel Hydrogen-Bonding Unit for Organic Field-Effect Transistors
title_sort synthesis of novel hydrogen-bonding unit for organic field-effect transistors
publisher University of Akron / OhioLINK
publishDate 2016
url http://rave.ohiolink.edu/etdc/view?acc_num=akron1460047707
work_keys_str_mv AT jinjiyang synthesisofnovelhydrogenbondingunitfororganicfieldeffecttransistors
_version_ 1719439444950384640

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