Evaluation of Tung Oil Based Reactive Diluents for ALKYD Coating Using Experimental Design

Bibliographic Details
Main Author:	Zheng, Yiming
Language:	English
Published:	University of Akron / OhioLINK 2014
Subjects:	Polymers Engineering
Online Access:	http://rave.ohiolink.edu/etdc/view?acc_num=akron1407946622

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spelling	ndltd-OhioLink-oai-etd.ohiolink.edu-akron14079466222021-08-03T06:26:57Z Evaluation of Tung Oil Based Reactive Diluents for ALKYD Coating Using Experimental Design Zheng, Yiming Polymers Engineering Tung oil based reactive diluents were prepared via Diels-Alder reactions with four acrylate dienophiles: methacryloxypropyl trimethoxysilane (MAS), 2,2,2-trifluoroethyl methacrylate (TFM), triallyl ether acrylate (TAEA), and glycidyl methacrylate (GMA). The final products were characterized by 1H NMR, 13C NMR, and mass spectroscopy. The conversion of each monomer (acrylate dienophile) was obtained through the 1H NMR integration calculation and GC-MS technique. For the first three tung oil based reactive diluents, a quaternary experimental design was employed to determine the influence of three reactive diluents on the thermal, mechanical properties of the alkyd coating system. The drying time could be altered with the addition of different types and concentrations of reactive diluents. The viscosity of alkyd binder decreased significantly with the incorporation of reactive diluents, indicating that those reactive diluents have the potential to replace organic solvent in alkyd system with modified tung oils. 2014-09-17 English text University of Akron / OhioLINK http://rave.ohiolink.edu/etdc/view?acc_num=akron1407946622 http://rave.ohiolink.edu/etdc/view?acc_num=akron1407946622 unrestricted This thesis or dissertation is protected by copyright: all rights reserved. It may not be copied or redistributed beyond the terms of applicable copyright laws.
collection	NDLTD
language	English
sources	NDLTD
topic	Polymers Engineering
spellingShingle	Polymers Engineering Zheng, Yiming Evaluation of Tung Oil Based Reactive Diluents for ALKYD Coating Using Experimental Design
author	Zheng, Yiming
author_facet	Zheng, Yiming
author_sort	Zheng, Yiming
title	Evaluation of Tung Oil Based Reactive Diluents for ALKYD Coating Using Experimental Design
title_short	Evaluation of Tung Oil Based Reactive Diluents for ALKYD Coating Using Experimental Design
title_full	Evaluation of Tung Oil Based Reactive Diluents for ALKYD Coating Using Experimental Design
title_fullStr	Evaluation of Tung Oil Based Reactive Diluents for ALKYD Coating Using Experimental Design
title_full_unstemmed	Evaluation of Tung Oil Based Reactive Diluents for ALKYD Coating Using Experimental Design
title_sort	evaluation of tung oil based reactive diluents for alkyd coating using experimental design
publisher	University of Akron / OhioLINK
publishDate	2014
url	http://rave.ohiolink.edu/etdc/view?acc_num=akron1407946622
work_keys_str_mv	AT zhengyiming evaluationoftungoilbasedreactivediluentsforalkydcoatingusingexperimentaldesign
_version_	1719436662669312000

Evaluation of Tung Oil Based Reactive Diluents for ALKYD Coating Using Experimental Design

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