| Summary: | Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Physics, 2004. === Includes bibliographical references (p. 125-144). === I present high-resolution X-ray grating spectroscopy of neutron stars in low-mass X-ray binaries (LMXBs) using instruments onboard the Chandra X-ray Observatory and the X-ray Multi-Mirror Mission (XMM-Newton). The first part of this thesis concentrates on results from the subset of LMXBs with orbital periods less than an hour, known as ultracompact binaries. Previous low-resolution X-ray spectra of four systems (4U 0614+091, 2S 0918-549, 4U 1543-624, and 4U 1850-087) all contain a broad residual near 0.7 keV which had been attributed to unresolved line emission. I show that this residual is due to an incorrect model of the intervening photoelectric absorption and can be accounted for by allowing a non-standard Ne/O abundance ratio in the intervening material. I propose that there is neon-rich material local to each binary and that the mass donor is a low-mass, neon-rich degenerate dwarf in an ultracompact binary. Follow-up spectroscopy of 2S 0918-549 and 4U 1543-624 with the High Energy Transmission Grating Spectrometer (HETGS) onboard Chandra and the Reflection Grating Spectrometer onboard XMM confirms the excess neutral neon absorption. Interestingly, the Ne/O ratio of 4U 1543-624 varies by a factor of three between the Chandra and XMMobservations, supporting the suggestion that some of the absorption originates local to the binaries. I also present X-ray spectroscopy of another ultracompact binary, the accretion-powered millisecond pulsar XTE J0929-314. No emission or absorption features are found in the high-resolution spectrum of this source, and the neutral absorption edge depths are consistent with the estimated interstellar absorption. The second part of this thesis uses LMXBs as probes of the interstellar medium (ISM). === (cont.) High-resolution X-ray studies of ISM absorption features can provide measurements of the relative abundances and ionization fractions of all the elements from carbon through iron. X- ray studies also probe the ISM on larger scales than is possible in the optical and ultraviolet wavebands. I present high-resolution spectroscopy of the oxygen K-shell ISM absorption edge in seven X-ray binaries using Chandra. The best-fit model consists of two absorption edges and five Gaussian absorption lines and can be explained by the recent theoretical calculations of K-shell absorption by neutral and ionized atomic oxygen. Significant oxygen features from dust or molecular components, suggested in previous studies, are not required by the Chandra spectra. These measurements also probe large-scale properties of the ISM, placing a limit on the velocity dispersion of the neutral lines of less than 200 km s-1 and constraining the interstellar ratio of O II/O I to approximately 0.1 and the ratio of O III/O I to less than 0.1. === by Adrienne Marie Juett. === Ph.D.
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