Probing of reaction mechanisms, and development of polymeric materials for lithium-air batteries

• Main Author: Amanchukwu, Chibueze Vincent
• Other Authors: Paula T. Hammond.
• Format: Others
• Language: English
• Published: Massachusetts Institute of Technology 2017
• Subjects: Chemical Engineering.
• Online Access: http://hdl.handle.net/1721.1/111419

Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemical Engineering, 2017. === Cataloged from PDF version of thesis. === Includes bibliographical references (pages 184-194). === Limiting the use of fossil fuels is vital to stemming climate change. Incorporation of renewable energy technologies into the grid, and the shift to electric vehicles for transportation increases the need for better energy storage media. Lithium-air (O₂) batteries are of great interest because they have high theoretical energy densities. However, conventional Li-O₂ batteries face challenges such as the use of volatile and flammable liquid electrolytes, side reactions between the electrolyte/electrode with oxygen reduction products, and high charging over-potentials that lead to poor cycle life. We address these challenges by developing non-flammable polymeric-based electrolytes and electrodes, and investigate their performance and stability in Li-O₂ batteries. In this thesis, we synthesized and studied the properties of a nonvolatile and nonflammable siloxane solid polymer electrolyte that can support Li-O₂ discharge, but show it is vulnerable to reaction with the desired Li2O₂ discharge product. We developed a screening tool that involves mixing commercial Li2O₂ with various polymers of interest for Li-O₂ batteries, and formulate polymer reactivity rules where the presence of electron-withdrawing groups on the polymer and adjacent hydrogen atoms make the polymer vulnerable to degradation. Of the polymers studied in contact with Li2O₂, poly(methyl methacrylate) was found to be stable, and then used as part of a gel polymer electrolyte with an ionic liquid (IL) and lithium salt. The Li/IL molar ratio in the GPE was shown to allow for a switch from a 2 e- to 1e- oxygen reduction chemistry, and the formation of ionic liquid-superoxide complexes as the discharge product. Exploiting this understanding of the influence of a bulky ionic liquid cation on the oxygen electrochemistry, we incorporate ammonium salts in a Li-O₂ battery and show it can also support discharge and lead to > 0.5 V reduction in charging overpotential when compared to lithium salts. Finally, we explore an electron conducting polymer electrode poly(3, 4- ethylenedioxythiophene) (PEDOT) as a Li-O₂ electrode and show the polymeric surface allows for oxygen reduction and Li2O₂ formation. Coupling fundamental understanding with material selection can empower the design of next generation Li-O₂ batteries. === by Chibueze Vincent Amanchukwu. === Ph. D.