Remote Hydroxylation of Triazene and Diazonium Containing Sulfones

C-H functionalization is an effective way to generate more reactive functionality from unactivated C-H bonds. Developments in this field aid in the synthesis of value- added compounds by shortening and/or simplifying total syntheses. The focus of my research has been the generation of a diazonium-be...

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Main Author:	Kimball, Elizabeth Ann
Other Authors:	Stanley, George
Format:	Others
Language:	en
Published:	LSU 2017
Subjects:	Chemistry
Online Access:	http://etd.lsu.edu/docs/available/etd-07092017-093759/

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spelling	ndltd-LSU-oai-etd.lsu.edu-etd-07092017-0937592017-07-22T03:56:18Z Remote Hydroxylation of Triazene and Diazonium Containing Sulfones Kimball, Elizabeth Ann Chemistry C-H functionalization is an effective way to generate more reactive functionality from unactivated C-H bonds. Developments in this field aid in the synthesis of value- added compounds by shortening and/or simplifying total syntheses. The focus of my research has been the generation of a diazonium-bearing aryl sulfone and subsequent optimization of a new remote hydroxylation procedure with relatively mild conditions. This remote hydroxylation procedure utilizes 4 W blue LEDs (λmax=455 nm) and [Ru(bpy)3]Cl2 to induce the generation of an aryl radical, succeeded by a selective sp3C- H hydrogen abstraction, and installation of an alcohol group via intermediacy of a carbocation. Stanley, George Ragains, Justin Vicente, Graca LSU 2017-07-21 text application/pdf http://etd.lsu.edu/docs/available/etd-07092017-093759/ http://etd.lsu.edu/docs/available/etd-07092017-093759/ en restricted I hereby certify that, if appropriate, I have obtained and attached herein a written permission statement from the owner(s) of each third party copyrighted matter to be included in my thesis, dissertation, or project report, allowing distribution as specified below. I certify that the version I submitted is the same as that approved by my advisory committee. I hereby grant to LSU or its agents the non-exclusive license to archive and make accessible, under the conditions specified below and in appropriate University policies, my thesis, dissertation, or project report in whole or in part in all forms of media, now or hereafter known. I retain all other ownership rights to the copyright of the thesis, dissertation or project report. I also retain the right to use in future works (such as articles or books) all or part of this thesis, dissertation, or project report.
collection	NDLTD
language	en
format	Others
sources	NDLTD
topic	Chemistry
spellingShingle	Chemistry Kimball, Elizabeth Ann Remote Hydroxylation of Triazene and Diazonium Containing Sulfones
description	C-H functionalization is an effective way to generate more reactive functionality from unactivated C-H bonds. Developments in this field aid in the synthesis of value- added compounds by shortening and/or simplifying total syntheses. The focus of my research has been the generation of a diazonium-bearing aryl sulfone and subsequent optimization of a new remote hydroxylation procedure with relatively mild conditions. This remote hydroxylation procedure utilizes 4 W blue LEDs (λmax=455 nm) and [Ru(bpy)3]Cl2 to induce the generation of an aryl radical, succeeded by a selective sp3C- H hydrogen abstraction, and installation of an alcohol group via intermediacy of a carbocation.
author2	Stanley, George
author_facet	Stanley, George Kimball, Elizabeth Ann
author	Kimball, Elizabeth Ann
author_sort	Kimball, Elizabeth Ann
title	Remote Hydroxylation of Triazene and Diazonium Containing Sulfones
title_short	Remote Hydroxylation of Triazene and Diazonium Containing Sulfones
title_full	Remote Hydroxylation of Triazene and Diazonium Containing Sulfones
title_fullStr	Remote Hydroxylation of Triazene and Diazonium Containing Sulfones
title_full_unstemmed	Remote Hydroxylation of Triazene and Diazonium Containing Sulfones
title_sort	remote hydroxylation of triazene and diazonium containing sulfones
publisher	LSU
publishDate	2017
url	http://etd.lsu.edu/docs/available/etd-07092017-093759/
work_keys_str_mv	AT kimballelizabethann remotehydroxylationoftriazeneanddiazoniumcontainingsulfones
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Remote Hydroxylation of Triazene and Diazonium Containing Sulfones

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