The total synthesis of (-)-ent-Anhydromyriocin 1,2 : a thesis

The total synthesis of (-)-ent-Anhydromyriocin 1,2 : a thesis

The optical antipode of anhydromyriocin, the (gamma)-lactone derived from the antibiotic myriocin, was synthesized from L-arabinose. The identity of myriocin and thermozymocidin was confirmed, and their relative and absolute stereochemistries were established. In contrast to its natural enantiomer,...

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Main Author: Payette, Daniel Ronald.
Format: Others
Language:en
Published: McGill University 1980
Subjects:
Myriocin.
Thermozymocidin.
Antibiotics.
Online Access:http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=68579
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spelling ndltd-LACETR-oai-collectionscanada.gc.ca-QMM.685792014-02-13T04:04:46ZThe total synthesis of (-)-ent-Anhydromyriocin 1,2 : a thesisPayette, Daniel Ronald.Myriocin.Thermozymocidin.Antibiotics.The optical antipode of anhydromyriocin, the (gamma)-lactone derived from the antibiotic myriocin, was synthesized from L-arabinose. The identity of myriocin and thermozymocidin was confirmed, and their relative and absolute stereochemistries were established. In contrast to its natural enantiomer, (-)-ent-anhydromyriocin showed but little antifungal activity.McGill University1980Electronic Thesis or Dissertationapplication/pdfenalephsysno: 000128007proquestno: AAINK52076Theses scanned by UMI/ProQuest.All items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated.Doctor of Philosophy (Department of Chemistry) http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=68579
collection NDLTD
language en
format Others
sources NDLTD
topic Myriocin.
Thermozymocidin.
Antibiotics.
spellingShingle Myriocin.
Thermozymocidin.
Antibiotics.
Payette, Daniel Ronald.
The total synthesis of (-)-ent-Anhydromyriocin 1,2 : a thesis
description The optical antipode of anhydromyriocin, the (gamma)-lactone derived from the antibiotic myriocin, was synthesized from L-arabinose. The identity of myriocin and thermozymocidin was confirmed, and their relative and absolute stereochemistries were established. In contrast to its natural enantiomer, (-)-ent-anhydromyriocin showed but little antifungal activity.
author Payette, Daniel Ronald.
author_facet Payette, Daniel Ronald.
author_sort Payette, Daniel Ronald.
title The total synthesis of (-)-ent-Anhydromyriocin 1,2 : a thesis
title_short The total synthesis of (-)-ent-Anhydromyriocin 1,2 : a thesis
title_full The total synthesis of (-)-ent-Anhydromyriocin 1,2 : a thesis
title_fullStr The total synthesis of (-)-ent-Anhydromyriocin 1,2 : a thesis
title_full_unstemmed The total synthesis of (-)-ent-Anhydromyriocin 1,2 : a thesis
title_sort total synthesis of (-)-ent-anhydromyriocin 1,2 : a thesis
publisher McGill University
publishDate 1980
url http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=68579
work_keys_str_mv AT payettedanielronald thetotalsynthesisofentanhydromyriocin12athesis
AT payettedanielronald totalsynthesisofentanhydromyriocin12athesis
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