Determination of C-C bond dissociation energies in 1-butyne and 1,2-butadiene.
Bonds are broken and formed in all chemical reactions. A knowledge of the dissociation energies of the relevant bonds helps one to predict the ease by which a given reaction may take place. It is obvious, therefore, that such information is useful in deciding which reactions should be included in th...
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ndltd-LACETR-oai-collectionscanada.gc.ca-QMM.1137622014-02-13T04:09:45ZDetermination of C-C bond dissociation energies in 1-butyne and 1,2-butadiene.Schaffer, Robert.Chemistry.Bonds are broken and formed in all chemical reactions. A knowledge of the dissociation energies of the relevant bonds helps one to predict the ease by which a given reaction may take place. It is obvious, therefore, that such information is useful in deciding which reactions should be included in the overall mechanism of a complex system. The dissociation energy of the bond R1-R2 in the molecule R1R2 is defined as the endothermicity of the reaction in which the bond R1-R2 is ruptured with the formation of two free radicals R1 and R2.McGill UniversitySehon, A. (Supervisor)1962Electronic Thesis or Dissertationapplication/pdfenalephsysno: NNNNNNNNNTheses scanned by McGill Library.All items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated.Doctor of Philosophy. (Department of Chemistry.) http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=113762 |
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Chemistry. Schaffer, Robert. Determination of C-C bond dissociation energies in 1-butyne and 1,2-butadiene. |
description |
Bonds are broken and formed in all chemical reactions. A knowledge of the dissociation energies of the relevant bonds helps one to predict the ease by which a given reaction may take place. It is obvious, therefore, that such information is useful in deciding which reactions should be included in the overall mechanism of a complex system. The dissociation energy of the bond R1-R2 in the molecule R1R2 is defined as the endothermicity of the reaction in which the bond R1-R2 is ruptured with the formation of two free radicals R1 and R2. |
author2 |
Sehon, A. (Supervisor) |
author_facet |
Sehon, A. (Supervisor) Schaffer, Robert. |
author |
Schaffer, Robert. |
author_sort |
Schaffer, Robert. |
title |
Determination of C-C bond dissociation energies in 1-butyne and 1,2-butadiene. |
title_short |
Determination of C-C bond dissociation energies in 1-butyne and 1,2-butadiene. |
title_full |
Determination of C-C bond dissociation energies in 1-butyne and 1,2-butadiene. |
title_fullStr |
Determination of C-C bond dissociation energies in 1-butyne and 1,2-butadiene. |
title_full_unstemmed |
Determination of C-C bond dissociation energies in 1-butyne and 1,2-butadiene. |
title_sort |
determination of c-c bond dissociation energies in 1-butyne and 1,2-butadiene. |
publisher |
McGill University |
publishDate |
1962 |
url |
http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=113762 |
work_keys_str_mv |
AT schafferrobert determinationofccbonddissociationenergiesin1butyneand12butadiene |
_version_ |
1716646465405714432 |