Determination of C-C bond dissociation energies in 1-butyne and 1,2-butadiene.
Bonds are broken and formed in all chemical reactions. A knowledge of the dissociation energies of the relevant bonds helps one to predict the ease by which a given reaction may take place. It is obvious, therefore, that such information is useful in deciding which reactions should be included in th...
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| Format: | Others |
| Language: | en |
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McGill University
1962
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| Online Access: | http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=113762 |
| Summary: | Bonds are broken and formed in all chemical reactions. A knowledge of the dissociation energies of the relevant bonds helps one to predict the ease by which a given reaction may take place. It is obvious, therefore, that such information is useful in deciding which reactions should be included in the overall mechanism of a complex system. The dissociation energy of the bond R1-R2 in the molecule R1R2 is defined as the endothermicity of the reaction in which the bond R1-R2 is ruptured with the formation of two free radicals R1 and R2. |
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