Phase Relations in the Fe-As-S System.

The phase relations in the Fe-As-S system at 600°0, studied in rigid silica glass tubes where a vapor phase is always present, are as follows: a liquid field extends along the S-As join from 100 to 22.8 +/- 0.2 weight per cent sulfur. An extensive pyrite-liquid-vapor field and a narrower pyrrhotite-...

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Bibliographic Details
Main Author: Clark, Lloyd A.
Other Authors: Stevenson, J.S. (Supervisor)
Format: Others
Language:en
Published: McGill University 1959
Subjects:
Online Access:http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=111734
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Summary:The phase relations in the Fe-As-S system at 600°0, studied in rigid silica glass tubes where a vapor phase is always present, are as follows: a liquid field extends along the S-As join from 100 to 22.8 +/- 0.2 weight per cent sulfur. An extensive pyrite-liquid-vapor field and a narrower pyrrhotite-liquid-vapor field are separated by the four-phase region pyrite-pyrrhotite-liquid-vapor in which the composition of the liquid is, in weight per cent, approximately As = 62.5, S = 37.5, and Fe = 0.11. [...]