Reactions of active nitrogen with ammonia, hydrazine and methylamine.

It is now well established that free radicals play an important part as intermediates in many chemical reactions. However, until 1929 the existence of free radicals was the subject of a vehement controversy. As early as 1834, the possible isolation of alkyl radicals through the action of potassium o...

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Main Author:	Freeman, Gordon. R.
Other Authors:	Winkler, C. (Supervisor)
Format:	Others
Language:	en
Published:	McGill University 1955
Subjects:	Chemistry.
Online Access:	http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=109956

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spelling	ndltd-LACETR-oai-collectionscanada.gc.ca-QMM.1099562014-02-13T04:06:22ZReactions of active nitrogen with ammonia, hydrazine and methylamine.Freeman, Gordon. R.Chemistry.It is now well established that free radicals play an important part as intermediates in many chemical reactions. However, until 1929 the existence of free radicals was the subject of a vehement controversy. As early as 1834, the possible isolation of alkyl radicals through the action of potassium on their chlorides or iodides was predicted (1). In 1900 Gomberg (2) attempted to prepare hexaphenylethane by the reaction of triphenylchlormethane with metallic magnesium, and obtained an unusually reactive material which he concluded was free triphenylmethyl.McGill UniversityWinkler, C. (Supervisor)1955Electronic Thesis or Dissertationapplication/pdfenalephsysno: NNNNNNNNNTheses scanned by McGill Library.All items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated.Doctor of Philosophy. (Department of Chemistry.) http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=109956
collection	NDLTD
language	en
format	Others
sources	NDLTD
topic	Chemistry.
spellingShingle	Chemistry. Freeman, Gordon. R. Reactions of active nitrogen with ammonia, hydrazine and methylamine.
description	It is now well established that free radicals play an important part as intermediates in many chemical reactions. However, until 1929 the existence of free radicals was the subject of a vehement controversy. As early as 1834, the possible isolation of alkyl radicals through the action of potassium on their chlorides or iodides was predicted (1). In 1900 Gomberg (2) attempted to prepare hexaphenylethane by the reaction of triphenylchlormethane with metallic magnesium, and obtained an unusually reactive material which he concluded was free triphenylmethyl.
author2	Winkler, C. (Supervisor)
author_facet	Winkler, C. (Supervisor) Freeman, Gordon. R.
author	Freeman, Gordon. R.
author_sort	Freeman, Gordon. R.
title	Reactions of active nitrogen with ammonia, hydrazine and methylamine.
title_short	Reactions of active nitrogen with ammonia, hydrazine and methylamine.
title_full	Reactions of active nitrogen with ammonia, hydrazine and methylamine.
title_fullStr	Reactions of active nitrogen with ammonia, hydrazine and methylamine.
title_full_unstemmed	Reactions of active nitrogen with ammonia, hydrazine and methylamine.
title_sort	reactions of active nitrogen with ammonia, hydrazine and methylamine.
publisher	McGill University
publishDate	1955
url	http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=109956
work_keys_str_mv	AT freemangordonr reactionsofactivenitrogenwithammoniahydrazineandmethylamine
_version_	1716645188746608640

Reactions of active nitrogen with ammonia, hydrazine and methylamine.

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