Preparation of Ruthenium and Iridium Pincer-Type Pyridylidenes

Preparation of Ruthenium and Iridium Pincer-Type Pyridylidenes

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A new POCOP pincer-type ligand was synthesized and characterized. This new ligand gave rise to the first POCOP pyridylidene pincer-type ruthenium and iridium complexes. Investigations into structural and electronic parameters of these newly generated compounds were conducted. Furthermore, we prepare...

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Main Author: Athanasopoulos, Aristidis Pantelis Telly
Language:en
Published: 2009
Subjects:
Pyridylidene
Pincer complex
Chemistry
Online Access:http://hdl.handle.net/10012/4651
id ndltd-LACETR-oai-collectionscanada.gc.ca-OWTU.10012-4651
record_format oai_dc
spelling ndltd-LACETR-oai-collectionscanada.gc.ca-OWTU.10012-46512013-10-04T04:09:08ZAthanasopoulos, Aristidis Pantelis Telly2009-08-31T17:44:44Z2009-08-31T17:44:44Z2009-08-31T17:44:44Z2009-08-19http://hdl.handle.net/10012/4651A new POCOP pincer-type ligand was synthesized and characterized. This new ligand gave rise to the first POCOP pyridylidene pincer-type ruthenium and iridium complexes. Investigations into structural and electronic parameters of these newly generated compounds were conducted. Furthermore, we prepared ruthenium dihydrogen and bis-dihydrogen complexes and studied them via deuterium labelling and low temperature NMR spectroscopy. These complexes were screened for catalysis in C-C coupling, C-H bond activation and ketone hydrogenation reactions.enPyridylidenePincer complexPreparation of Ruthenium and Iridium Pincer-Type PyridylidenesThesis or DissertationChemistryMaster of ScienceChemistry
collection NDLTD
language en
sources NDLTD
topic Pyridylidene
Pincer complex
Chemistry
spellingShingle Pyridylidene
Pincer complex
Chemistry
Athanasopoulos, Aristidis Pantelis Telly
Preparation of Ruthenium and Iridium Pincer-Type Pyridylidenes
description A new POCOP pincer-type ligand was synthesized and characterized. This new ligand gave rise to the first POCOP pyridylidene pincer-type ruthenium and iridium complexes. Investigations into structural and electronic parameters of these newly generated compounds were conducted. Furthermore, we prepared ruthenium dihydrogen and bis-dihydrogen complexes and studied them via deuterium labelling and low temperature NMR spectroscopy. These complexes were screened for catalysis in C-C coupling, C-H bond activation and ketone hydrogenation reactions.
author Athanasopoulos, Aristidis Pantelis Telly
author_facet Athanasopoulos, Aristidis Pantelis Telly
author_sort Athanasopoulos, Aristidis Pantelis Telly
title Preparation of Ruthenium and Iridium Pincer-Type Pyridylidenes
title_short Preparation of Ruthenium and Iridium Pincer-Type Pyridylidenes
title_full Preparation of Ruthenium and Iridium Pincer-Type Pyridylidenes
title_fullStr Preparation of Ruthenium and Iridium Pincer-Type Pyridylidenes
title_full_unstemmed Preparation of Ruthenium and Iridium Pincer-Type Pyridylidenes
title_sort preparation of ruthenium and iridium pincer-type pyridylidenes
publishDate 2009
url http://hdl.handle.net/10012/4651
work_keys_str_mv AT athanasopoulosaristidispantelistelly preparationofrutheniumandiridiumpincertypepyridylidenes
_version_ 1716600257552318464

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