STUDIES OF THE COORDINATION CHEMISTRY AND CATALYTIC ACTIVITY OF RHODIUM AND RUTHENIUM N-HETEROCYCLIC CARBENE COMPLEXES
The side-on dioxygen adducts of N-heterocyclic carbene (NHC) containing rhodium complexes, [ClRh(IPr)2(O2)] and [ClRh(IMes)2(O2)], previously synthesized in our laboratories possess a square planar geometry and O-O bond lengths of 1.323(3) and 1.341(4) Å, respectively. Both of these attributes are...
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| Language: | en en |
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2010
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| Online Access: | http://hdl.handle.net/1974/6048 |