Dinuclear dinitrogen and mononuclear paramagnetic complexes of zirconium

The basic focus of this work is the use of the tridentate, mixed donor ligand, [N(SiMe₂CH₂PR₂)₂]⁻ abbreviated as PNP, to generate zirconium compounds that contain dinitrogen ligands in unusual bonding modes, or to allow the stabilization of the very rare zirconium(III) oxidation state. The approa...

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Bibliographic Details
Main Author: Mylvaganam, Murugesapillai
Language:English
Published: 2009
Online Access:http://hdl.handle.net/2429/6864