17-electron chromium nitrosyl complexes
Reaction of [CpCr(NO)I]₂ with an excess of ammonia or allylamine yields the complex salts [CpCr(NO)L₂]⁺[I]⁻ (L = NH₃, NH₂C₃H₅) . Heating these salts results in loss of L and formation of the neutral complexes, CpCr(NO)(L)I. In contrast, reaction of [CpCr(NO)I]₂ with the bulkier amine NH₂CMe₃ affo...
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| Language: | English |
| Published: |
2009
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| Online Access: | http://hdl.handle.net/2429/4804 |