Studies towards the synthesis of functionalized aryl fluorides : transition metal catalyzed cross-coupling and fluorination of organoboron reagents

This thesis covers several synthetic approaches to the generation of highly functionalized aryl fluorides. PtCl₂(SMe₂)₂ and PtCl₂(DMSO)₂ have been applied to catalytic methylation of polyfluoroaryl imines as user-friendly precatalysts. These complexes have demonstrated high selectivity for ortho C-F...

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Bibliographic Details
Main Author: Sun, Duo
Language:English
Published: University of British Columbia 2013
Online Access:http://hdl.handle.net/2429/43839