Zirconium complexes of cyclopentene-bridged diamidophosphine ligands for dinitrogen activation
The synthesis of two new diiminophosphine proligands, CY⁵[NPN]DMPH₂ (DMP = 2,6-Me₂C₆H₃) and CY⁵[NPN]DIPPH₂ (DIPP = 2,6-iPr2C₆H₃), is reported. These two proligands feature a cyclopentane ring linker between the phosphine and imino donors. The precursors of the proligands were prepared from cyclop...
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| Language: | English |
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University of British Columbia
2010
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| Online Access: | http://hdl.handle.net/2429/28114 |