Desenvolvimento e caracteriza??o de biolubrificante a partir do ?leo de carna?ba aditivado com micropart?culas e nanopart?culas de grafite

• Main Author: Cavalcanti, Synara Lucien de Lima
• Other Authors: 12391085400
• Language: Portuguese
• Published: PROGRAMA DE P?S-GRADUA??O EM ENGENHARIA MEC?NICA 2018
• Subjects: CNPQ::ENGENHARIAS::ENGENHARIA MECANICA; ?leo de carna?ba; Biolubrificante; Nanopart?culas de grafite; Efici?ncia de lubrifica??o; EPEDRA
• Online Access: https://repositorio.ufrn.br/jspui/handle/123456789/24939

Submitted by Automa??o e Estat?stica ([e-mail]) on 2018-03-20T17:21:12Z No. of bitstreams: 1 SynaraLucienDeLimaCavalcanti_TESE.pdf: 4087598 bytes, checksum: 3742f5acd410c92f39cb86294da47261 (MD5) === Approved for entry into archive by Arlan Eloi Leite Silva ([e-mail]) on 2018-03-22T13:32:34Z (GMT) No. of bitstreams: 1 SynaraLucienDeLimaCavalcanti_TESE.pdf: 4087598 bytes, checksum: 3742f5acd410c92f39cb86294da47261 (MD5) === Made available in DSpace on 2018-03-22T13:32:34Z (GMT). No. of bitstreams: 1 SynaraLucienDeLimaCavalcanti_TESE.pdf: 4087598 bytes, checksum: 3742f5acd410c92f39cb86294da47261 (MD5) Previous issue date: 2018-01-29 === Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior (CAPES) === O lubrificante ? respons?vel por reduzir o desgaste relativo ao atrito, proteger o metal contra a oxida??o, corros?o e dissipar o calor excessivo, tornando-se essencial para o equil?brio de um sistema mec?nico, consequentemente prolongando a vida ?til de tal sistema. A origem dos ?leos lubrificantes ?, em geral, mineral sendo extra?dos a partir do petr?leo. Mas a busca por uma nova fonte de produ??o de lubrificantes faz-se necess?rio para suprir futuras demandas e diminuir os poss?veis danos ambientais. O ?leo vegetal ? um recurso renov?vel e biodegrad?vel, e a sua utiliza??o implica em vantagens nos aspectos ambientais, sociais e econ?micos, apresentando-se como uma mat?ria prima de grande potencial para a produ??o de lubrificantes. De acordo com a literatura, o ?leo vegetal de carna?ba apresenta excelentes propriedades e desempenho superior em rela??o a sua capacidade de reduzir o desgaste relativo ao atrito e a sua capacidade de dissipa??o de calor quando comparado com um ?leo comercial similar. Este projeto tem como objetivo desenvolver e caracterizar um material biolubrificante aditivado com micropart?culas e nanopart?culas de grafite a partir do ?leo de carna?ba. O ?leo de carna?ba in natura foi submetido a uma an?lise de estabilidade oxidativa, estabilidade t?rmica, e an?lise de sua composi??o qu?mica. As micropart?culas e nanopart?culas de grafite foram desenvolvidas em um moinho planet?rio de alta energia e caracterizadas atrav?s das an?lises em MEV, MEV-FEG, DRX, FRX e EDX. As concentra??es de grafite nas amostras de biolubrificante foram 0g/L, 0,5g/L e 2g/L. Para caracterizar o biolubrificante foram realizadas as an?lises da microestrutura, de massa espec?fica, viscosidade, ?ndice de acidez, estabilidade t?rmica, condutividade t?rmica e resistividade t?rmica. A efici?ncia de lubrifica??o e a capacidade de dissipa??o de calor por gradiente de temperatura foram analisadas em um sistema mec?nico simulado em bancada (EPEDRA). Diante das an?lises conclui-se que o ?leo de carna?ba in natura, BiolubC 2.0M e BiolubC 2.0N podem ser utilizados eficientemente como biolubrificantes, observadas as caracter?sticas e necessidades do sistema mec?nico. === The lubricant is responsible for reducing friction-related wear, protecting the metal against oxidation, corrosion and dissipating excessive heat, making it essential for the balance of a mechanical system, thereby prolonging the life of such a system. The origin of the lubricating oils is, in general, mineral being extracted from petroleum. But the search for a new source of lubricant production is necessary to meet future demands and reduce possible environmental damages. Vegetable oil is a renewable and biodegradable resource and its use implies advantages in environmental, social and economic aspects, presenting as a raw material of great potential for the production of lubricants. According to the literature, the carnauba oil has excellent properties and superior performance in relation to its ability to reduce friction-related wear and its heat dissipation capacity when compared to a similar commercial oil. This project aims to develop and characterize a biolubricant material added with microparticles and graphite nanoparticles from carnauba oil. The in natura carnauba oil was subjected to oxidative stability, thermal stability, and analysis of its chemical composition. The microparticles and nanoparticles were developed in a high energy planetary mill and characterized by SEM, DRX, FRX and EDX analysis. The graphite concentrations in the biolubricant samples are 0g/L, 0,5g/L and 2g/L. In order to characterize the biolubricant, microstructure, specific gravity, viscosity, acidity index, thermal stability, thermal conductivity and thermal resistivity analyzes were performed. The lubrication efficiency and the heat dissipation capacity by temperature gradient were analyzed in a simulated mechanical bench system. In view of the analysis, it is concluded that the in natura carnauba oil, BiolubC 2.0M and BiolubC 2.0N can be efficiently used as biolubricants, observing the characteristics and needs of the mechanical system.