Catalisadores bifuncionais ? base de silicoaluminofosfato e fosfatos de ni?bio para emprego em rea??es de hidroisomeriza??o e hidrocraqueamento do n-hexadecano

• Main Author: Bassan, ?ria Almeida Leal
• Other Authors: 50942611004
• Language: Portuguese
• Published: Universidade Federal do Rio Grande do Norte 2016
• Subjects: CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA; SAPO; Materiais mesoporosos; Hidroisomeriza??o; Hidrocraqueamento; N-hexadecano
• Online Access: http://repositorio.ufrn.br/handle/123456789/21135

Submitted by Automa??o e Estat?stica ([e-mail]) on 2016-08-09T22:44:46Z No. of bitstreams: 1 IriaAlmeidaLealBassan_TESE.pdf: 3143028 bytes, checksum: 970a070c1dc06ffd41a2333aff70d989 (MD5) === Approved for entry into archive by Arlan Eloi Leite Silva ([e-mail]) on 2016-08-10T22:36:43Z (GMT) No. of bitstreams: 1 IriaAlmeidaLealBassan_TESE.pdf: 3143028 bytes, checksum: 970a070c1dc06ffd41a2333aff70d989 (MD5) === Made available in DSpace on 2016-08-10T22:36:43Z (GMT). No. of bitstreams: 1 IriaAlmeidaLealBassan_TESE.pdf: 3143028 bytes, checksum: 970a070c1dc06ffd41a2333aff70d989 (MD5) Previous issue date: 2015-11-20 === Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior (CAPES) === Os lubrificantes e cortes de destilados m?dios possuem, normalmente, grandes quantidades de n-parafinas que lhes confere valores de pontos de congelamento e de fluidez mais elevados. Nesse sentido, a remo??o de n-parafinas de cadeias longas de ?leos lubrificantes e do diesel ? essencial para se obter um produto com boas propriedades de fluxo a frio. O desenvolvimento de novos catalisadores que apresentem estabilidade t?rmica e atividade catal?tica frente ? rea??o de hidroisomeriza??o ainda ? um desafio. Sendo assim, silicoaluminofosfatos (SAPO) foram sintetizados por diferentes rotas. Utilizou-se, tamb?m, tratamento p?s-s?ntese para obten??o de estruturas h?bridas e realizou-se s?nteses com direcionadores (soft templates e hard templates) de estrutura mesoporosa. Os catalisadores foram impregnados com platina, pelo m?todo de impregna??o ?mida, para posterior avalia??o catal?tica frente ? rea??o de hidroisomeriza??o do n-hexadecano. Al?m dos SAPO, fosfatos de ni?bio (NbP) tamb?m foram impregnados com platina e avaliados na referida rea??o. Ap?s a impregna??o, esses catalisadores foram caracterizados por difra??o de Raios X (DRX), adsor??o de nitrog?nio, espectroscopia no infravermelho com piridina adsorvida (IV-PY), microscopia eletr?nica de varredura (MEV), microscopia eletr?nica de transmiss?o (MET) e resson?ncia magn?tica nuclear do 29Si (29Si-RMN). Os resultados de caracteriza??o por DRX mostraram que foi poss?vel a obten??o de SAPO mesoestruturados. No entanto, para as s?nteses com soft template houve colapso da estrutura ap?s a remo??o dos direcionadores org?nicos. Mesmo assim, esses catalisadores apresentaram atividade catal?tica. Foi poss?vel a obten??o de materiais h?bridos por meio das s?nteses do SAPO-11 realizadas com hard templates e tamb?m por meio de tratamentos p?s- s?ntese em amostras de SAPO-11. Ademais, os NbP apresentaram DRX caracter?sticos de materiais amorfos, com alta acidez e foram ativos na convers?o do n-hexadecano. === Lubricants and cutting middle distillates typically have large amounts of n-paraffins to increase its freezing point and fluidity. Accordingly, the removal of n-paraffins of long chain lubricants oils and diesel is essential to get a product with good cold flow properties. The development of new catalysts, which exhibit thermal stability and catalytic activity for the hydroisomerization reaction is still a challenge. Thus, silicoaluminophosphates (SAPO) were synthesized by different routes. Have been used also post-synthesis treatment for obtaining hybrid structures and others synthesis have been carried out with mesoporous template (soft and hard-template). Therefore, SAPO have been impregnated with H2PtCl6 solution by the incipient wetness method. Then assessments of catalytic activities in hydroisomerization and hydrocracking reactions of hexadecane have been held. Besides SAPO, niobium phosphate - NbP - were also impregnated with platinum and evaluated in the same reaction. After impregnation, these catalysts have been characterized by X-ray diffraction (XRD), nitrogen adsorption, infrared spectroscopy with adsorbed pyridine (IV-PY), scanning electron microscopy (SEM) and resonance nuclear magnetic 29Si (29Si-NMR). The characterization results by XRD have shown that it has been possible to obtain mesoporous SAPOs. However, for the syntheses with soft template there was collapse of the structure after removal of the organic template. Even so, these catalysts have been actives. It was possible to obtain hybrid materials through the synthesis of SAPO-11 made with hard templates and by means of post-synthesis treatments samples of SAPO-11. Moreover, NbP has shown characteristic XRD of amorphous materials, with high acidity and were active in the conversion of hexadecane.