Espectrometria de emiss?o ?ptica com plasma indutivamente acoplado aliada ? quimiometria na determina??o de ?ons met?licos no molusco Mytella falcata para discrimina??o de estu?rios potiguares

Made available in DSpace on 2014-12-17T15:42:07Z (GMT). No. of bitstreams: 1 George Queiroz de Brito_DISSERT.PDF: 4768865 bytes, checksum: 4923b44db97f60fb6edf6bd685c61440 (MD5) Previous issue date: 2010-02-26 === This work examined the possibility of using mussel Mytella falcata as bioindicator s...

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Bibliographic Details
Main Author: Brito, George Queiroz de
Other Authors: CPF:31482015404
Format: Others
Language:Portuguese
Published: Universidade Federal do Rio Grande do Norte 2014
Subjects:
Online Access:http://repositorio.ufrn.br:8080/jspui/handle/123456789/17711
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Summary:Made available in DSpace on 2014-12-17T15:42:07Z (GMT). No. of bitstreams: 1 George Queiroz de Brito_DISSERT.PDF: 4768865 bytes, checksum: 4923b44db97f60fb6edf6bd685c61440 (MD5) Previous issue date: 2010-02-26 === This work examined the possibility of using mussel Mytella falcata as bioindicator sample to detect metal ions in several estuaries potiguares, since species substances that accumulate in their tissues due to its characteristics filter feeders have been used for environmental monitoring. The chemometrics by principal components analysis was used to reduce the size of the original data in order to establish a pattern of distribution of metal ion. Samples were collected at three different points in the estuaries Curimata?, Guara?ra-Papeba, Potengi, Galinhos-Guamar? and Piranhas-Assu having been marked with the location using GPS (Global Positioning System). The determination of humidity content and digestion of the samples were performed using methods described in the Compendium of analytical standards of the Institute Adofo Lutz (2005) and the determination of metal ions of the elements Al, Ba, Cd, Cr, Cu, Mn, Ni, Pb, Sn and Zn were performed by optical emission spectrometry with inductively coupled plasma as described by USEPA method 6010C. The results show that it is possible to use this molluscum Mytella falcata in the estuaries of Rio Grande do Norte for the determination of metal ions. The data were subjected to principal components analysis (PCA) which enabled us to verify the distribution pattern of the metal ions studied in several estuaries potiguares and group them according to the metal ions in common with and relate them to the activities in each region === Este trabalho procurou verificar a possibilidade do uso do molusco bivalve Mytella falcata como amostra bioindicadora para detectar ?ons met?licos em v?rios estu?rios potiguares, pois as esp?cies que acumulam subst?ncias em seus tecidos devido as suas caracter?sticas filtradoras tem sido utilizadas para o monitoramento ambiental. A quimiometria atrav?s da an?lise de componentes principais foi utilizada para reduzir a dimens?o dos dados originais com a finalidade de estabelecer um padr?o de distribui??o dos ?ons met?licos estudados. As amostras foram coletadas em tr?s pontos diferentes nos estu?rios Curimata?, Guara?ra-Papeba, Potengi, Galinhos-Guamar? e Piranhas-Assu tendo o local sido marcado com a utiliza??o de GPS (Global Positioning System). A determina??o do teor de umidade e a digest?o das amostras foram realizadas segundo metodologia descrita no comp?ndio de normas anal?ticas do Instituto Adofo Lutz (2005) e a determina??o dos ?ons met?licos dos elementos Al, Ba, Cd, Cr, Cu, Mn, Ni, Pb, Sn e Zn foram realizadas por espectrometria de emiss?o ?tica com plasma acoplado indutivamente como descrito pela metodologia USEPA 6010C. Os resultados obtidos mostram que ? poss?vel utilizar o molusco Mytella falcata presente nos estu?rios do Estado do Rio Grande do Norte para a determina??o de ?ons met?licos. Os dados foram submetidos ? an?lise de componentes principais (PCA) o que possibilitou verificarmos o padr?o de distribui??o dos ?ons met?licos estudados nos v?rios estu?rios potiguares e agrup?-los de acordo com os ?ons met?licos em comum e relacionar a presen?a com as atividades desenvolvidas em cada regi?o