Estudo da oxida??o do metabissulfito de s?dio contido no efluente da carcinicultura

• Main Author: Albuquerque, Liana Filgueira
• Other Authors: CPF:08580772800
• Format: Others
• Language: Portuguese
• Published: Universidade Federal do Rio Grande do Norte 2014
• Subjects: Carcinicultura; Despesca; Sulfito; Sulfato; Oxida??o; Shrimp farming; Fishing; Sulphite; Sulphate; Oxidation; CNPQ::ENGENHARIAS::ENGENHARIA QUIMICA
• Online Access: http://repositorio.ufrn.br:8080/jspui/handle/123456789/15759

Made available in DSpace on 2014-12-17T15:01:16Z (GMT). No. of bitstreams: 1 LianaFA.pdf: 575157 bytes, checksum: 8650946fd949f8eb8297ea9541d69e42 (MD5) Previous issue date: 2005-01-18 === Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior === The shrimp farming is a process of creation of shrimp that has been growing rapidly in the country, occupying a meaningful space in the Brazilian exporting. In 2003, this activity presented a volume of 60 millions of tons and 220 millions of dollars, being the main generator of employment and income of the primary sector of the northeast economy. However, it is a new activity with c.a. five years in the Rio Grande do Norte State and therefore needs investment in the technological area. Among the wastewaters of this activity, the sulphite solution is being usually applied in the process of fishing, i.e. retrieval of the shrimps from the farming. The aim of this work is to present the oxidation experimental results of the sulphite that may be and to determine what it s the most efficient method, trough laboratory experiments. The measurements were carried out in a mixing reactor inserting air and with hydrogen peroxide addition with and without UV light. The solutions were prepared synthetically with concentrations found in the wastewater of fishing and also collected in locu. The oxidation process using air was monitorated by iodometric analysis for the sulphite and the oxidation using hydrogen peroxide was evaluated with turbidimetric analysis for sulphate, by spectrophotometer. The sulphite was totally oxidized in both processes. The experimental results permit to conclude that the oxidation by hydrogen peroxide is more efficient and allowed to determine the optimum operational conditions in terms of concentration and time of treatment === A carcinicultura, processo de cria??o de camar?o em cativeiro, vem crescendo rapidamente no pa?s, ocupando um espa?o significativo na exporta??o brasileira. Em 2003, essa atividade apresentou um volume de 60 milh?es de ton e um faturamento de 220 milh?es de d?lares sendo tamb?m, o principal gerador de emprego e renda do setor prim?rio da economia nordestina. Por?m, por ser uma atividade nova, com pouco mais de 5 anos no Estado do Rio Grande do Norte, faz-se necess?rio investimento na ?rea tecnol?gica. Entre os efluentes dessa atividade tem-se a solu??o aquosa de sulfito, normalmente utilizada no processo de despesca retirada dos camar?es do viveiro. O objetivo desse trabalho ? apresentar os resultados da oxida??o do sulfito e concluir qual o m?todo mais eficiente entre os testados em laborat?rio. Os experimentos foram realizados em um reator injetando-se ar difuso e outro com adi??o de per?xido de hidrog?nio, na aus?ncia e presen?a de luz UV. As solu??es utilizadas foram: sint?ticas, com concentra??es semelhantes ao efluente da despesca e, coletadas in locu. A oxida??o com ar foi monitorada por an?lise iodom?trica do sulfito e com per?xido por an?lise turbidim?trica do sulfato, com espectrofot?metro. O sulfito foi totalmente oxidado em ambos os processos. Os resultados experimentais possibilitaram concluir que a oxida??o do sulfito com per?xido foi a mais eficiente e permitiram encontrar as condi??es ?timas de concentra??o do per?xido, de acordo com o tempo de tratamento