Frontiers in the organometallic chemistry of silver: Accessing new structures and reactivity through sterically demanding, electron-rich N-heterocyclic carbene ligands
The synthesis and characterization of novel complexes of silver supported by sterically demanding, highly electrophilic N-heterocyclic carbene (NHC) ancillary ligands, is described. Stable hydride, fluoride, alkoxide, alkyl, aryl, and alkynyl complexes are characterized by NMR spectroscopy and X-ray...
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| Format: | Others |
| Language: | en_US |
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Georgia Institute of Technology
2016
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| Online Access: | http://hdl.handle.net/1853/54451 |