Synthesis of Chiral Surfactants for Enantioselective Organic Synthesis.
The first step of the synthesis of the hydrocarbon-based chiral surfactant (2) involved the methylation of (S)-leucinol to give (2S)-N-hexadecyl-N,N-dimethyl-(1-hydroxy-4-methyl-1-pentyl)-2-ammonium bromide (2.92g, 67%). The chiral surfactant was synthesized by reacting (2S)-N,N-dimethyl-2-amino-4-m...
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| Format: | Others |
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Digital Commons @ East Tennessee State University
2003
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| Online Access: | https://dc.etsu.edu/etd/798 https://dc.etsu.edu/cgi/viewcontent.cgi?article=1955&context=etd |