Bismuth(III) benzohydroxamates: powerful anti-bacterial activity against Helicobacter pylori and hydrolysis to a unique Bi34 oxido-cluster [Bi34O22(BHA)22(H-BHA)14(DMSO)6]
Reaction of BiPh3 or Bi(OtBu)3 with benzohydroxamic acid (H2-BHA) results in formation of novel mono- and di-anionic hydroxamato complexes; [Bi2(BHA)3]∞1, [Bi(H-BHA)3] 2, [Bi(BHA)(H-BHA)] 3, all of which display nM activity against Helicobacter pylori. Subsequent dissolution of [Bi2(BHA)3]∞ in DMSO/...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Universitätsbibliothek Chemnitz
2015
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| Subjects: | |
| Online Access: | http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-161727 http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-161727 http://www.qucosa.de/fileadmin/data/qucosa/documents/16172/c4cc07329k.pdf http://www.qucosa.de/fileadmin/data/qucosa/documents/16172/c4cc07329k1.pdf http://www.qucosa.de/fileadmin/data/qucosa/documents/16172/c4cc07329k2.cif http://www.qucosa.de/fileadmin/data/qucosa/documents/16172/signatur.txt.asc |