Bismuth(III) benzohydroxamates: powerful anti-bacterial activity against Helicobacter pylori and hydrolysis to a unique Bi34 oxido-cluster [Bi34O22(BHA)22(H-BHA)14(DMSO)6]

Bismuth(III) benzohydroxamates: powerful anti-bacterial activity against Helicobacter pylori and hydrolysis to a unique Bi34 oxido-cluster [Bi34O22(BHA)22(H-BHA)14(DMSO)6]

Reaction of BiPh3 or Bi(OtBu)3 with benzohydroxamic acid (H2-BHA) results in formation of novel mono- and di-anionic hydroxamato complexes; [Bi2(BHA)3]∞1, [Bi(H-BHA)3] 2, [Bi(BHA)(H-BHA)] 3, all of which display nM activity against Helicobacter pylori. Subsequent dissolution of [Bi2(BHA)3]∞ in DMSO/...

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Bibliographic Details
Main Authors: Pathak, Amita, Blair, Victoria L., Ferrero, Richard L., Mehring, Michael, Andrews, Philip C.
Other Authors: Royal Society of Chemistry,
Format: Article
Language:English
Published: Universitätsbibliothek Chemnitz 2015
Subjects:
Bismut
Carboxylate
Cluster
Helicobacter Pylori
antibakterielle Materialien
Technische Universität Chemnitz
Allianzlizenz
bismuth
carboxylates
cluster
helicobacter pylori
anti-bacterial materials
ddc:530
Online Access:http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-161727
http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-161727
http://www.qucosa.de/fileadmin/data/qucosa/documents/16172/c4cc07329k.pdf
http://www.qucosa.de/fileadmin/data/qucosa/documents/16172/c4cc07329k1.pdf
http://www.qucosa.de/fileadmin/data/qucosa/documents/16172/c4cc07329k2.cif
http://www.qucosa.de/fileadmin/data/qucosa/documents/16172/signatur.txt.asc

Internet

http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-161727
http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-161727
http://www.qucosa.de/fileadmin/data/qucosa/documents/16172/c4cc07329k.pdf
http://www.qucosa.de/fileadmin/data/qucosa/documents/16172/c4cc07329k1.pdf
http://www.qucosa.de/fileadmin/data/qucosa/documents/16172/c4cc07329k2.cif
http://www.qucosa.de/fileadmin/data/qucosa/documents/16172/signatur.txt.asc

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