Molecular traffic control in porous nanoparticles
We investigate the conditions for reactivity enhancement of catalytic processes in porous solids by use of molecular traffic control (MTC) as a function of reaction rate and grain size. With dynamic Monte-Carlo simulations, continuous-time random walk theory and solutions of the Master equation we o...
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| Format: | Article |
| Language: | English |
| Published: |
Universitätsbibliothek Leipzig
2016
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| Online Access: | http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-195217 http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-195217 http://www.qucosa.de/fileadmin/data/qucosa/documents/19521/diff_fund_2%282005%2910.pdf |
| Summary: | We investigate the conditions for reactivity enhancement of catalytic processes in porous solids by use of molecular traffic control (MTC) as a function of reaction rate and grain size. With dynamic Monte-Carlo simulations, continuous-time random walk theory and
solutions of the Master equation we obtain a quantitative description of the MTC effect for a network of intersecting single-file channels in a wide range of grain parameters. |
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