Size dependence of solute diffusivity and Stokes-Einstein relationship: effect of van der Waals interaction
Size dependence of solute diffusivity has been investigated using molecular dynamics simulations for a range of solute radii in a binary mixture consisting of solute and solvent species. We demonstrate that the Stokes-Einstein relationship between self diffusivity and solute radius breaks down over...
| Main Authors: | , |
|---|---|
| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
Universitätsbibliothek Leipzig
2016
|
| Subjects: | |
| Online Access: | http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-193071 http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-193071 http://www.qucosa.de/fileadmin/data/qucosa/documents/19307/diff_fund_7%282007%2911.pdf |