The Intramolecular Buchner Reaction of α-Diazo-β-Ketonitriles: Development and Application to the Total Synthesis of (+)-Salvileucalin B
<p>Since its discovery in 1896, the Buchner reaction has fascinated chemists for more than a century. The highly reactive nature of the carbene intermediates allows for facile dearomatization of stable aromatic rings, and provides access to a diverse array of cyclopropane and seven-membered ri...
Internet
https://thesis.library.caltech.edu/7847/1/Nani-R-R-2013thesis.pdfNani, Roger Rauhauser (2013) The Intramolecular Buchner Reaction of α-Diazo-β-Ketonitriles: Development and Application to the Total Synthesis of (+)-Salvileucalin B. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/2KGP-7X92. https://resolver.caltech.edu/CaltechTHESIS:06062013-031825238 <https://resolver.caltech.edu/CaltechTHESIS:06062013-031825238>