Silicon-directed carbon-carbon bond forming reactions

Silicon-directed carbon-carbon bond forming reactions

<p>It is shown that O-silyl ketene N,O-acetals react with aldehydes, without catalysis, to form aldol-type products with high diastereoselectivity. For example, the prolinolderived O-silyl ketene N,O-acetal 7 reacts with benzaldehyde to form the anti aldol product 9 with >98% diastereoselec...

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Bibliographic Details
Main Author: Widdowson, Katherine
Format: Others
Published: 1992
Online Access:https://thesis.library.caltech.edu/6693/1/Widdowson_k_1992.pdf
Widdowson, Katherine (1992) Silicon-directed carbon-carbon bond forming reactions. Dissertation (Ph.D.), California Institute of Technology. https://resolver.caltech.edu/CaltechTHESIS:09282011-115011728 <https://resolver.caltech.edu/CaltechTHESIS:09282011-115011728>

Internet

https://thesis.library.caltech.edu/6693/1/Widdowson_k_1992.pdf
Widdowson, Katherine (1992) Silicon-directed carbon-carbon bond forming reactions. Dissertation (Ph.D.), California Institute of Technology. https://resolver.caltech.edu/CaltechTHESIS:09282011-115011728 <https://resolver.caltech.edu/CaltechTHESIS:09282011-115011728>

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