Real-time measurements of a bimolecular reaction
A method is described for the initiation of a bimolecular reaction with a laser. This allows the time resolution of bimolecular kinetics with ultrafast laser spectroscopy. Such kinetics are described for the case of H + CO_2 => OH + CO. The rise in OH is measured and examined via the proper int...
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1989
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| Online Access: | https://thesis.library.caltech.edu/5680/1/Sipes_cn_1989.pdf Sipes, Christopher N. (1989) Real-time measurements of a bimolecular reaction. Master's thesis, California Institute of Technology. doi:10.7907/3527-zy08. https://resolver.caltech.edu/CaltechTHESIS:04022010-095849815 <https://resolver.caltech.edu/CaltechTHESIS:04022010-095849815> |
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ndltd-CALTECH-oai-thesis.library.caltech.edu-5680 |
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ndltd-CALTECH-oai-thesis.library.caltech.edu-56802021-04-17T05:01:54Z https://thesis.library.caltech.edu/5680/ Real-time measurements of a bimolecular reaction Sipes, Christopher N. A method is described for the initiation of a bimolecular reaction with a laser. This allows the time resolution of bimolecular kinetics with ultrafast laser spectroscopy. Such kinetics are described for the case of H + CO_2 => OH + CO. The rise in OH is measured and examined via the proper intermediate-mediated kinetics -- the "biphasic" expression. The effect of restricting the impact parameter of the hydrogen atom on the carbon dioxide is also considered. 1989 Thesis NonPeerReviewed application/pdf en other https://thesis.library.caltech.edu/5680/1/Sipes_cn_1989.pdf Sipes, Christopher N. (1989) Real-time measurements of a bimolecular reaction. Master's thesis, California Institute of Technology. doi:10.7907/3527-zy08. https://resolver.caltech.edu/CaltechTHESIS:04022010-095849815 <https://resolver.caltech.edu/CaltechTHESIS:04022010-095849815> https://resolver.caltech.edu/CaltechTHESIS:04022010-095849815 CaltechTHESIS:04022010-095849815 10.7907/3527-zy08 |
| collection |
NDLTD |
| language |
en |
| format |
Others
|
| sources |
NDLTD |
| description |
A method is described for the initiation of a bimolecular reaction with a laser. This allows the time resolution of bimolecular kinetics with ultrafast laser spectroscopy. Such kinetics are described for the case of
H + CO_2 => OH + CO. The rise in OH is measured and examined via the proper intermediate-mediated kinetics -- the "biphasic" expression. The effect of restricting the impact parameter of the hydrogen atom on the carbon dioxide is also considered. |
| author |
Sipes, Christopher N. |
| spellingShingle |
Sipes, Christopher N. Real-time measurements of a bimolecular reaction |
| author_facet |
Sipes, Christopher N. |
| author_sort |
Sipes, Christopher N. |
| title |
Real-time measurements of a bimolecular reaction |
| title_short |
Real-time measurements of a bimolecular reaction |
| title_full |
Real-time measurements of a bimolecular reaction |
| title_fullStr |
Real-time measurements of a bimolecular reaction |
| title_full_unstemmed |
Real-time measurements of a bimolecular reaction |
| title_sort |
real-time measurements of a bimolecular reaction |
| publishDate |
1989 |
| url |
https://thesis.library.caltech.edu/5680/1/Sipes_cn_1989.pdf Sipes, Christopher N. (1989) Real-time measurements of a bimolecular reaction. Master's thesis, California Institute of Technology. doi:10.7907/3527-zy08. https://resolver.caltech.edu/CaltechTHESIS:04022010-095849815 <https://resolver.caltech.edu/CaltechTHESIS:04022010-095849815> |
| work_keys_str_mv |
AT sipeschristophern realtimemeasurementsofabimolecularreaction |
| _version_ |
1719396791895457792 |