Development of Iminium-Activation Technologies and the Total Synthesis of (+)-Frondosin B
<p>The enantioselective imidazolidinone-catalyzed epoxidation of α,β-unsaturated aldehydes has been accomplished via a novel 1,4-heteroconjugate addition reaction using hypervalent iodine reagents. Development of an “internal syringe pump” protocol for the slow release of iodosobenzene from an...