I. Matrix Isolation of 1,1-Diazenes. II. Distance, Temperature, and Dynamic Solvent Effects on Electron Transfer Reactions
<p>Part I: Investigations of the reactive intermediates known as 1, 1-diazenes or aminonitrenes are reported. These unstable species were generated by UV photolysis of appropriately substituted carbamoyl azides under matrix isolation conditions. Four systems were investigated: three cyclic dia...