Enantioselective Organocatalytic Friedel-Crafts Alkylations of Heterocycles and Electron-Rich Benzenes

Enantioselective Organocatalytic Friedel-Crafts Alkylations of Heterocycles and Electron-Rich Benzenes

<p>The development of the first organocatalytic asymmetric Friedel-Crafts alkylation is described in the context of conjugate additions of pyrroles to a,b-unsaturated aldehydes. Catalytic amounts of chiral imidazolidinone salts are used to activate the electrophile component via reversible fo...

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Bibliographic Details
Main Author: Paras, Nick Anthony
Format: Others
Language:en
Published: 2004
Online Access:https://thesis.library.caltech.edu/2353/1/NParas.pdf
Paras, Nick Anthony (2004) Enantioselective Organocatalytic Friedel-Crafts Alkylations of Heterocycles and Electron-Rich Benzenes. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/EFG2-7V87. https://resolver.caltech.edu/CaltechETD:etd-06012004-190154 <https://resolver.caltech.edu/CaltechETD:etd-06012004-190154>

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https://thesis.library.caltech.edu/2353/1/NParas.pdf
Paras, Nick Anthony (2004) Enantioselective Organocatalytic Friedel-Crafts Alkylations of Heterocycles and Electron-Rich Benzenes. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/EFG2-7V87. https://resolver.caltech.edu/CaltechETD:etd-06012004-190154 <https://resolver.caltech.edu/CaltechETD:etd-06012004-190154>

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