Ultrafast Photoreduction of Nitric Oxide Synthase by Electron Tunneling Wires
The Gray group has a long-standing interest in the study of methods for rapid delivery of electrons to enzyme active sites. This thesis describes picosecond to nanosecond reduction of the heme active site of the inducible nitric oxide synthase oxygenase domain (iNOSoxy) bound to Re- and Ru-diimine...
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