Vibrational relaxation times of gaseous mixtures of diatomic molecules and their effect on rocket performance
The present methods available for the determination of the magnitudes of the vibrational relaxation times of molecules are discussed and the recently developed theory of Schwartz, Slawsky, and Herzfeld is used to compute the variation with temperature of the collisional vibrational excitation probab...
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ndltd-CALTECH-oai-thesis.library.caltech.edu-1292019-12-22T03:05:36Z Vibrational relaxation times of gaseous mixtures of diatomic molecules and their effect on rocket performance Penny, Harmon C The present methods available for the determination of the magnitudes of the vibrational relaxation times of molecules are discussed and the recently developed theory of Schwartz, Slawsky, and Herzfeld is used to compute the variation with temperature of the collisional vibrational excitation probabilities of mixtures of N2 and 02, and of H2 and HF. The results are used to estimate the extent of vibrational temperature lag in the hydrogen-fluorine rocket motor. 1954 Thesis NonPeerReviewed application/pdf https://thesis.library.caltech.edu/129/1/Penny_hc_1954.pdf https://resolver.caltech.edu/CaltechETD:etd-01122004-094512 Penny, Harmon C (1954) Vibrational relaxation times of gaseous mixtures of diatomic molecules and their effect on rocket performance. Engineer's thesis, California Institute of Technology. doi:10.7907/Y2D2-M834. https://resolver.caltech.edu/CaltechETD:etd-01122004-094512 <https://resolver.caltech.edu/CaltechETD:etd-01122004-094512> https://thesis.library.caltech.edu/129/ |
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The present methods available for the determination of the magnitudes of the vibrational relaxation times of molecules are discussed and the recently developed theory of Schwartz, Slawsky, and Herzfeld is used to compute the variation with temperature of the collisional vibrational excitation probabilities of mixtures of N2 and 02, and of H2 and HF. The results are used to estimate the extent of vibrational temperature lag in the hydrogen-fluorine rocket motor.
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Penny, Harmon C |
spellingShingle |
Penny, Harmon C Vibrational relaxation times of gaseous mixtures of diatomic molecules and their effect on rocket performance |
author_facet |
Penny, Harmon C |
author_sort |
Penny, Harmon C |
title |
Vibrational relaxation times of gaseous mixtures of diatomic molecules and their effect on rocket performance |
title_short |
Vibrational relaxation times of gaseous mixtures of diatomic molecules and their effect on rocket performance |
title_full |
Vibrational relaxation times of gaseous mixtures of diatomic molecules and their effect on rocket performance |
title_fullStr |
Vibrational relaxation times of gaseous mixtures of diatomic molecules and their effect on rocket performance |
title_full_unstemmed |
Vibrational relaxation times of gaseous mixtures of diatomic molecules and their effect on rocket performance |
title_sort |
vibrational relaxation times of gaseous mixtures of diatomic molecules and their effect on rocket performance |
publishDate |
1954 |
url |
https://thesis.library.caltech.edu/129/1/Penny_hc_1954.pdf Penny, Harmon C (1954) Vibrational relaxation times of gaseous mixtures of diatomic molecules and their effect on rocket performance. Engineer's thesis, California Institute of Technology. doi:10.7907/Y2D2-M834. https://resolver.caltech.edu/CaltechETD:etd-01122004-094512 <https://resolver.caltech.edu/CaltechETD:etd-01122004-094512> |
work_keys_str_mv |
AT pennyharmonc vibrationalrelaxationtimesofgaseousmixturesofdiatomicmoleculesandtheireffectonrocketperformance |
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1719304270836137984 |