Evidence for a Stereospecific 1,2-Elimination Reaction in a 1,1-Diazene. Synthesis and Decomposition of [N-Phenyl-(Threo-(and Erythro)-2-Deuterio-1-Methylpropl)Amino]Nitrene

Evidence for a Stereospecific 1,2-Elimination Reaction in a 1,1-Diazene. Synthesis and Decomposition of [N-Phenyl-(Threo-(and Erythro)-2-Deuterio-1-Methylpropl)Amino]Nitrene

<p>CHAPTER 1:</p> <p>The mechanism of the formal 1,2-elimination reaction of 1,1-diazenes to alkenes is examined. 'fue syntheses and decomposition of [N-phenyl-(1-methylpropyl)amino]nitrene (6), [N-phenyl(erythro-2-deuterio-1-methylpropyl)amino]nitrene (7) and [N-phenyl-(th...

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Bibliographic Details
Main Author: Duan, Daniel C.
Format: Others
Language:en
Published: 1983
Online Access:https://thesis.library.caltech.edu/11786/1/Duan_DC_1983.pdf
Duan, Daniel C. (1983) Evidence for a Stereospecific 1,2-Elimination Reaction in a 1,1-Diazene. Synthesis and Decomposition of [N-Phenyl-(Threo-(and Erythro)-2-Deuterio-1-Methylpropl)Amino]Nitrene. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/zbfn-1t36. https://resolver.caltech.edu/CaltechTHESIS:09032019-103344869 <https://resolver.caltech.edu/CaltechTHESIS:09032019-103344869>

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