(2,2-Dimethylcyclopropyl)carbinyl Grignard Reagents and the Reactivity of Osmium Tetraoxide and Peroxycarboxylic Acids with Low Valent Iridium Compounds
<p>The formation and rearrangement of Grignard reagents from (2,2-dimethylcyclopropyl)carbinyl halide have been studied. The Grignard reagent from the chloride, 2,2-dimethyl-3-butenyl-1-magnesium chloride, demonstrates the carbanionic influence on the Grignard rearrangement. The bromide yielde...
Internet
https://thesis.library.caltech.edu/11271/1/Audett_JD_1984.pdfAudett, Jay Douglas (1984) (2,2-Dimethylcyclopropyl)carbinyl Grignard Reagents and the Reactivity of Osmium Tetraoxide and Peroxycarboxylic Acids with Low Valent Iridium Compounds. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/z4g9-cb82. https://resolver.caltech.edu/CaltechTHESIS:11122018-101217195 <https://resolver.caltech.edu/CaltechTHESIS:11122018-101217195>