I. Walden Inversions Involving the Isomeric 2,3-Butanediamenes and Related Compounds. II. An Experimental Test of Kirkwood's Theory of Optical Rotatory Power. III. Zero-Point Vibrational Contributions to the Optical Activity of Isotopically Asymmetric Molecules

<p>It has been demonstrated that reaction of ammonia with 1,2-dimethylethyleneimine is attended by single Walden inversion and that the analogous reaction of ammonia with 2,3-epoxybutane very probably proceeds in the same way. This result and other evidence have been used to assign configu...

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Bibliographic Details
Main Author: Fickett, Wildon
Format: Others
Published: 1952
Online Access:https://thesis.library.caltech.edu/10478/1/Fickett_W_1952.pdf
Fickett, Wildon (1952) I. Walden Inversions Involving the Isomeric 2,3-Butanediamenes and Related Compounds. II. An Experimental Test of Kirkwood's Theory of Optical Rotatory Power. III. Zero-Point Vibrational Contributions to the Optical Activity of Isotopically Asymmetric Molecules. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/YA4K-H648. https://resolver.caltech.edu/CaltechTHESIS:10032017-114803981 <https://resolver.caltech.edu/CaltechTHESIS:10032017-114803981>