Ligand-Controlled Asymmetric Arylation of Aliphatic α-Amino Anion Equivalents
A palladium-catalyzed asymmetric arylation of 9-aminofluorene-derived imines using a chiral dialkylbiaryl phosphine as the supporting ligand has been developed. This transformation allows for enantioselective access to a diverse range of α-branched benzylamines.
Main Authors: | Zhu, Ye (Contributor), Buchwald, Stephen Leffler (Contributor) |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry (Contributor) |
Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2015-04-09T18:29:18Z.
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Subjects: | |
Online Access: | Get fulltext |
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