Versatile Reactivity of a Solvent-Coordinated Diiron(II) Compound: Synthesis and Dioxygen Reactivity of a Mixed-Valent Fe [superscript II] Fe [superscript III] Species

Versatile Reactivity of a Solvent-Coordinated Diiron(II) Compound: Synthesis and Dioxygen Reactivity of a Mixed-Valent Fe [superscript II] Fe [superscript III] Species

A new, DMF-coordinated, preorganized diiron compound [Fe[subscript 2](N-Et-HPTB)(DMF)[subscript 4]](BF[subscript 4])[subscript 3] (1) was synthesized, avoiding the formation of [Fe(N-Et-HPTB)](BF4)2 (10) and [Fe2(N-Et-HPTB)(μ-MeCONH)](BF[subscript 4])[subscript 2] (11), where N-Et-HPTB is the anion...

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Main Authors: Majumdar, Amit (Contributor), Apfel, Ulf-Peter (Contributor), Jiang, Yunbo (Author), Moenne-Loccoz, Pierre (Author), Lippard, Stephen J. (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2015-02-24T20:55:47Z.
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