Tetrakis(acetonitrile)copper(I) hydrogen oxalate-oxalic acid-acetonitrile (1/0.5/0.5)

In the title compound, [Cu(CH[subscript 3]CN)[subscript 4]](C[subscript 2]HO[subscript 4])·0.5C[subscript 2]H[subscript 2]O[subscript 4]·0.5CH[subscript 3]CN, the Cu[superscript I] ion is coordinated by the N atoms of four acetonitrile ligands in a slightly distorted tetrahedral environment. The oxa...

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Bibliographic Details
Main Authors: Royappa, A. Timothy (Author), Stepherson, Jacob R. (Author), Vu, Oliver D. (Author), Royappa, Andrew D. (Author), Stern, Charlotte L. (Author), Mueller, Peter (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: 2014-09-10T19:43:51Z.
Subjects:
Online Access:Get fulltext
LEADER 01626 am a22002653u 4500
001 89419
042 |a dc 
100 1 0 |a Royappa, A. Timothy  |e author 
100 1 0 |a Massachusetts Institute of Technology. Department of Chemistry  |e contributor 
100 1 0 |a Mueller, Peter  |e contributor 
700 1 0 |a Stepherson, Jacob R.  |e author 
700 1 0 |a Vu, Oliver D.  |e author 
700 1 0 |a Royappa, Andrew D.  |e author 
700 1 0 |a Stern, Charlotte L.  |e author 
700 1 0 |a Mueller, Peter  |e author 
245 0 0 |a Tetrakis(acetonitrile)copper(I) hydrogen oxalate-oxalic acid-acetonitrile (1/0.5/0.5) 
260 |c 2014-09-10T19:43:51Z. 
856 |z Get fulltext  |u http://hdl.handle.net/1721.1/89419 
520 |a In the title compound, [Cu(CH[subscript 3]CN)[subscript 4]](C[subscript 2]HO[subscript 4])·0.5C[subscript 2]H[subscript 2]O[subscript 4]·0.5CH[subscript 3]CN, the Cu[superscript I] ion is coordinated by the N atoms of four acetonitrile ligands in a slightly distorted tetrahedral environment. The oxalic acid molecule lies across an inversion center. The acetonitrile solvent molecule is disordered across an inversion center and was refined with half occupancy. In the crystal, the hydrogen oxalate anions and oxalic acid molecules are linked via O-H...O hydrogen bonds, forming chains along [010]. 
520 |a University of West Florida. Department of Chemistry 
520 |a University of West Florida. Office of Research and Sponsored Programs 
520 |a University of West Florida. Office of Undergraduate Research 
546 |a en_US 
655 7 |a Article 
773 |t Acta Crystallographica Section E Structure Reports Online