Nickel-Catalyzed Carbon-Carbon Bond-Forming Reactions of Unactivated Tertiary Alkyl Halides: Suzuki Arylations
The first Suzuki cross-couplings of unactivated tertiary alkyl electrophiles are described. The method employs a readily accessible catalyst (NiBr[subscript 2]·diglyme/4,4'-di-tert-butyl-2,2'-bipyridine, both commercially available) and represents the initial example of the use of a group...
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Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2014-01-27T15:43:01Z.
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Subjects: | |
Online Access: | Get fulltext |