Synthesis of Tungsten Oxo Alkylidene Complexes

Reaction of W(O)[subscript 2](CH[subscript 2]-t-Bu)[subscript 2](bipy) with a mixture of ZnCl[subscript 2](dioxane), PMe[subscript 2]Ph, and trimethylsilyl chloride in toluene at 100 °C produced the known tungsten oxo alkylidene complex W(O)(CH-t-Bu)Cl[subscript 2](PMe[subscript 2]Ph)[subscript 2] (...

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Bibliographic Details
Main Authors: Peryshkov, Dmitry (Contributor), Schrock, Richard Royce (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2014-01-27T13:33:19Z.
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