Molybdenum Triamidoamine Systems. Reactions Involving Dihydrogen Relevant to Catalytic Reduction of Dinitrogen
[HIPTN[subscript 3]N]Mo(N[subscript 2]) (MoN[subscript 2]) ([HIPTN[subscript 3]N][superscript 3−] = [(HIPTNCH2CH2)3N]3− where HIPT = 3,5-(2,4,6-i-Pr[subscript 3]C[subscript 6]H[subscript 2])[subscript 2]C[subscript 6]H[subscript 3]) reacts with dihydrogen slowly (days) at 22 °C to yield [HIPTN[subsc...
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Format: | Article |
Language: | English |
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American Chemical Society (ACS),
2013-11-22T18:04:17Z.
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Online Access: | Get fulltext |