Nickel-Catalyzed Enantioselective Cross-Couplings of Racemic Secondary Electrophiles That Bear an Oxygen Leaving Group
To date, effective nickel-catalyzed enantioselective cross-couplings of alkyl electrophiles that bear oxygen leaving groups have been limited to reactions of allylic alcohol derivatives with Grignard reagents. In this Communication, we establish that, in the presence of a nickel/pybox catalyst, a va...
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Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2013-11-08T19:22:50Z.
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Subjects: | |
Online Access: | Get fulltext |