Synthesis of Heterocycles via Pd-Ligand Controlled Cyclization of 2-Chloro-N-(2-vinyl)aniline: Preparation of Carbazoles, Indoles, Dibenzazepines and Acridines
The Pd-catalyzed condensation of 2-bromostyrene and 2-chloroaniline derivatives yields stable diphenylamine intermediates, which are selectively converted to five-, six-, or seven-membered heteroaromatics (indoles, carbazoles, acridines, and dibenzazepines). The selectivity of these intramolecular t...
Main Authors: | Tsvelikhovsky, Dmitry (Contributor), Buchwald, Stephen Leffler (Contributor) |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry (Contributor), Buchwald, Stephen L. (Contributor) |
Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2012-08-03T12:49:22Z.
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Subjects: | |
Online Access: | Get fulltext |
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