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01372 am a22002293u 4500 |
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|a Tsvelikhovsky, Dmitry
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|a Massachusetts Institute of Technology. Department of Chemistry
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|a Buchwald, Stephen L.
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|a Tsvelikhovsky, Dmitry
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|a Buchwald, Stephen Leffler
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|a Buchwald, Stephen Leffler
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|a Synthesis of Heterocycles via Pd-Ligand Controlled Cyclization of 2-Chloro-N-(2-vinyl)aniline: Preparation of Carbazoles, Indoles, Dibenzazepines and Acridines
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|b American Chemical Society (ACS),
|c 2012-08-03T12:49:22Z.
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|z Get fulltext
|u http://hdl.handle.net/1721.1/71969
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|a The Pd-catalyzed condensation of 2-bromostyrene and 2-chloroaniline derivatives yields stable diphenylamine intermediates, which are selectively converted to five-, six-, or seven-membered heteroaromatics (indoles, carbazoles, acridines, and dibenzazepines). The selectivity of these intramolecular transformations is uniquely ligand-controlled and offers efficient routes to four important classes of heterocycles from a common precursor.
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|a National Institutes of Health (U.S.) (GM-58160)
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|a Novartis AG
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|a en_US
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|a Article
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|t Journal of the American Chemical Society
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